Home > File-Chap10-Page6 > Table of Contents > New Articles > Article: Will Lithium-Ion batteries power the new millennium? > Order Book > Article: Is the ‘smart’ battery help or deterrent? > Chapter 5 > Chapter 10 > Introduction > Chapter 1 > Getting the most of your batteries > Article: Memory, myth or fact? > About the Author > Chapter 14 > Getting the most of your batteries > Neue Artikel > ¿Las baterías de Litio-Ion energizaran el nuevo milenio? > Article: What is the perfect battery? > Chapter 7 > Werden Lithium-Ion Akkus sich im neuen Millennium behaupten? > Article: Wann wurde die Batterie erfunden? > Chapter 9 > FAQ > Links > Part 2 > Part 3 > Contact Us > Search Tips > Chapter 6 > Chapter 6 > Author's Note > Chapter 9 > Chapter 8 > Chapter 3 > Chapter 2 > Chapter 12 > Chapter 13 > Chapter 11 > Chapter 15 > Advanced Search > Article: Can the Lead Acid battery compete in modern times? > Article: The Secrets of Battery Runtime > Article: The Fuel Cell, Is it Ready? > Article: Choosing a battery that will last > Article: The Secrets of Battery Runtime > Article: Memory, myth or fact? > Getting the most of your batteries > Getting the most of your batteries > The Cost of Battery Power > Getting the most of your batteries > Article: The 'Green Light' Lies > The changing demands of modern battery testers > Getting the most of your batteries > The Cost of Battery Power > The Cost of Battery Power > Getting the most of your batteries > Not all chargers are alike > Article: Battery testers for modern batteries > Article: Do battery returns need to be a million dollar problem? > Getting the most of your batteries > Articles Nouveaux > Svenska articlar > Articulos Nuevos > Progrès décisif dans le test rapide des batteries > Welcher Akku hält länger? > Est-ce que les batteries au lithium-ion alimenteront le nouveau millenaire? > Was begrenzt die Betriebszeit eines Akkus? > Les Secrets de la durée de fonctionnement d'une batterie > Werden Lithium-Ion Akkus sich im neuen Millennium behaupten? > Getting the most of your batteries > Le Voyant vert n'indique pas la vérité > Getting the most of your batteries > Descubrimiento en Pruebas Rapidas de Baterias > Tous les chargeurs ne sont pas identiques > Article: ¿La batería de plomo compite en los tiempos modernos? > The Cost of Battery Power > Getting the most of your batteries > Article: ¿Cuándo se inventó la batería? > Getting the most of your batteries > Getting the most of your batteries > Getting the most of your batteries > Article: Akku-Tester für moderne Akkus! > ¿Cómo seleccionar una batería que dure? > Getting the most of your batteries > El secreto del tiempo de duración en las baterías > Article: Akku-Pflege von Anfang bis Ende > Getting the most of your batteries > Getting the most of your batteries > Article: Prenez soin de vos batteries de leur naissance a leur retraite > Getting the most of your batteries > Getting the most of your batteries > Das grüne Licht trügt > Getting the most of your batteries > Une Solution au mystère de la batterie > Nicht alle Ladegeräte sind gleichwertig > Getting the most of your batteries > Akku-Geheimnis gelöst! > Getting the most of your batteries > Getting the most of your batteries > No todos los cargadores son iguales > Getting the most of your batteries > El misterio de la batería resuelto > Article: El cuidado de sus baterías desde que nacen hasta que se retiran > ¿Las devoluciones de baterías tienen que ser un problema de un millón de dólares? > Getting the most of your batteries > La Luz Verde Miente > Article: Batterianalysutrustningar för moderna batterier > Getting the most of your batteries > Article: Probadores de baterias para baterias modernas > Getting the most of your batteries > Part 1 > Site Map > Chapter 8 > Chapter 7 > Chapter 4 > Chapter 10 > Chapter 16 > Article: When was the battery invented? > Article: The Li-Polymer battery: substance or hype? > Article: Breakthrough in battery quick testing > Article: When was the battery invented? > Getting the most of your batteries Home | Site Map| Contact Us
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Figure 3 illustrates a normal battery in which the acid is equally distributed form top to bottom. This battery provides good performance because the correct acid concentration surrounds the plates. Figure 4 shows a stratified battery in which the acid concentration is light on top and heavy on the bottom. A light acid limits plate activation, promotes corrosion and reduces performance. High acid concentration on the bottom, on the other hand, artificially raises the open circuit voltage. The battery appears fully charged but provides a low CCA. High acid concentration also promotes sulfation and decreases the already low conductivity further. If unchecked, such a condition will eventually lead to a user-induced battery failure.

Figure 3: Normal battery
The acid is equally distributed from the top to the bottom in the cell and provides maximum CCA and capacity.
Figure 4: Stratified battery
The acid concentration is light on top and heavy on the bottom. High acid concentration artificially raises the open circuit voltage. The battery appears fully charged but has a low CCA. Excessive acid concentration induces sulfation on the lower half of the plates.

Allowing the battery to rest for a few days, applying a shaking motion or tipping the unit over tends to correct the problem. A topping charge by which the 12-volt battery is brought up to 16 volts for one to two hours also reverses the acid stratification. The topping charge also reduces sulfation caused by high acid concentration. Careful attention is needed to keep the battery from heating up and losing excessive electrolyte through hydrogen gassing. Always charge the battery in a well-ventilated room. Accumulation of hydrogen gas can lead to an explosion. Unlike many other gases, hydrogen is odorless and can only be detected with measuring devices.

Acid stratification is difficult to measure, even with the EIS technology. Non-invasive testers simply take a snapshot, average the measurements and spit out the results. Stratified batteries tend to show higher state-of-charge readings because of elevated voltage. On preliminary tests, the Spectro CA-12 also shows slightly higher CCA and capacity readings than normal. After letting the battery rest, the capacity tends to normalize. This may be due to diffusion effects in the stratified battery as a result of resting. Little information is available on how long a stratified battery needs to rest to improve the condition. It is known, however, that higher temperatures will hasten the diffusion process.

Ideally, a battery tester should indicate the level of acid stratification; sulfation, surface charge and other such condition and display how to correct the problem. This feature is not yet possible. Much research is being done in offering more complete battery evaluation without the need to apply a full discharge. This knowledge can then be applied to other battery systems, such as traction, military, marine, aviation and stationary batteries


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